Calorimetric study of solid state reactions

Functional diversity in templated solid state reactions

Manganese Antimonate: Facile solid state synthesis, characterization and its application for Biginelli reactions

Nanostructured Mn2Sb2O7 powders were synthesized via stoichiometric1:1 Mn:Sb molar ratio solid state reaction at different reactions temperatures for 8 h using MnSO4.H2O and Sb2O3 as raw materials. The synthesized materials were characterized by powder X-ray diffraction (PXRD) technique. Structural analyses were performed by the FullProf program employing profile matching with constant scale fa...

Application of solid-state kinetics to desolvation reactions

Mathematical methods have been developed to evaluate solid-state kinetics. They generally fall into two categories: model-fitting or model-free (isoconversional). Modelfitting methods determine the kinetic triplet (model, frequency factor and activation energy) whereas isoconversional (model-free) methods generate the activation energy as a function of reaction progress without modelistic assum...

Kinetics of consecutive reactions in the solid state:

The thermal and kinetic aspects of solid state decomposition reactions can be complex and posses a large number of parameters to investigate. The determination of the activation energies for the several intermediates in the thermal decomposition is particularly sensitive to the overlap in thermal decomposition traces. To overcome this problem we have undertaken the detailed kinetic analysis of ...

Perovskites by Design: A Toolbox of Solid-State Reactions

In recent years, many soft-chemical reactions of layered perovskites have been reported, and they can be classified into sets of similar reactions. Simple ion-exchange and intercalation reactions replace or modify the interlayer cations of layered perovskites, and more complex metathesis reactions replace interlayer cations with cationic structural units. Topochemical condensation reactions tha...